Corrosion is either chemical or electrochemical in nature. The distinction between chemical and electrochemical corrosion is based on the corrosion causing mechanism. Chemical corrosion is the direct result of exposure of a material to a chemical and is governed by the kinetics of chemical reactions.
Electrochemical corrosion is the dissolution of a metal through the oxidation process and can be defined as "degradation of a metal by an electrochemical reaction with its environment". This phomena also known as galvanic corrision.
The basic unit in which electrochemical reactions occur is the electrolytic cell. An electrolytic cell consists of three components;
- Anode
- Cathode
- Electrolyte
The anode is the site of oxidation and therefore the site of corrosion. The anode and cathode are electrically connected. The medium surrounding the anode and cathode is the electrolyte. In the absence of any one of these components, the electrochemical corrosion reaction will stop.
Any metal when immersed in an electrically conductive fluid, has a specific electrical potential that is measurable as a voltage and each metal has a different electrical potential when immersed in the same electrolyte such as sea water.
According to the potential difference of these two metals, the current flows from higher voltage metal to the lower one. This action raises the voltage of the lower-voltage metal above its natural potential. To establish the equilibrium, the lower-voltage metal discharges a current in to the electrolyte.
Table of Galvanic Series in Sea Water |
Range of Corrosion Potential
|
|
Magnesium and Magnesium Alloys |
-1,60V to -1,63V
|
Zinc |
-0,98V to -1,03V
|
Aluminum Alloys |
-0,76V to -1,00V
|
Mild Steel |
-0,60V to -0,71V
|
Wrought Iron |
-0,60V to -0,71V
|
Cast Iron |
-0,60V to -0,71V
|
Aisi 410 Stainless Steel - Active in Water |
0,46V to -0,58V
|
Aisi 304 Stainless Steel - Active in Water |
0,46V to -0,58V
|
Aisi 316 Stainless Steel - Active in Water |
-0,43V to -0,54V
|
Inconel - Active in Water |
-0,35V to -0,46V |
Aluminum Bronze (92%Cu-8%Al) |
-0,31V to -0,42V |
Naval Brass (60%Cu-39%Zn) |
-0,30V to -0,40V |
Yellow Brass (65%Cu-35%Zn) |
-0,30V to -0,40V |
Red Brass (85%Cu-15%Zn) |
-0,30V to -0,40V |
Tin |
-0,31V to -0,33V |
|
Copper |
-0,30V to -0,57V |
Lead-Tin Solder (50%-50%) |
-0,28V to -0,37V |
Admiralty Brass (76%Cu-28%Zn-1%Sn) |
-0,28V to -0,36V |
Aluminum Brass (76%Cu-22%Zn-2%Al) |
-0,28V to -0,36V |
Manganese Bronze |
-0,27V to -0,34V |
Silicon Bronze
|
-0,26V to -0,29V |
Aisi410 Stainless Steel - Passive in Water |
-0,26V to -0,35V |
Lead |
-0,19V to -0,25V |
Inconel (78%Ni-13,5%Cr-6%Fe) - Passive in Wayer |
-0,14V to -0,17V |
Nickel 200 |
-0,10V to -0,20V |
Aisi304 Stainless Steel - Passive in Water |
-0,05V to -0,10V |
Monel 400 (70%Ni-305Cu) |
-0,04V to -0,14V |
Aisi316 Stainless Steel - Passive in Water |
0,00v to -0,10V |
Titanium |
-0,05V to +0,06V |
Platinium |
+0,19V to +0,25V |
Graphite |
+0,20V to +0,30V |
Table.1) Galvanic series for some metals and alloys in sea water. There is a greater likelihood for galvanic corrosion between the two connected metals when the difference of the electrical potential is greater between them. [3]
The current passes through the electrolyte back to the higher-voltage metal and completes the electrical circuit between the two pieces. The current flowing through the electrolyte is generated by an electrochemical reaction that steadily consumes the lower-voltage metal a process. This is the galvanic corrosion.
References1. Corrosion Basics and Computer Modeling, 1986, V.G. DeGiorgi 2. Corrosion for Students of Science and Engineering, 1988, K. R. Trethewey - J. Chamberlain 3. Corrosion in Sea Water - Professional Boat Builder - December/January, 1995, Nigel Calder
|